The 24-year-old posted a picture of herself sitting next to the Hollywood megastar at the Golden Globes and The National Enquirer claims Angelina was ‘furious.’

As Brad, 52, sat looking forwards in his black tie back in January, Selena was pictured looking giggly as she looked incredible in her white off-shoulder dress.

Not happy: Angelina Jolie was reportedly furious when Selena Gomez posted this flirty Instagram at the Golden Globes with Brad Pitt back in January

A source told the site: ‘Angie blew a gasket when she saw Selena’s Instagram, and heard through friends about how Brad and Selena flirted so shamelessly.

‘Now Selena is bragging to everyone that Brad is gung ho to make another movie with her. Selena is going around jokingly calling Brad “my future husband,” and Angie is obviously none too pleased.”‘

According to the publication Angie demanded that Brad didn’t work with the young star again.

The actress cited irreconcilable differences as she filed for divorce from the actor following a 12 year relationship on September 15 – ‘for the health of the family’

The Instagram snap came after Selena talked about having a soft spot for the father of six at the time.

She told reporters on the red carpet that she was seeking him out, saying: ‘I’m not going to lie. It’s nice to look at all of the hot guys I admire.

‘I’m trying to find Ryan Gosling and Brad Pitt right now!’

MailOnline has contacted a representative for Selena Gomez and Angelina Jolie.

Back in 2013, Selena even went as far as to say that she was so nervous around him at the MTV Awards, she hid under a table.

Gorgeous girl: Back in 2013, Selena even went as far as to say that she was so nervous around him at the MTV Awards, she hid under a table

In an interview with Ellen DeGeneres shortly afterwards, Selena said Brad requested a meeting with her backstage after the show – pictured on stage at the awards

In an interview with Ellen DeGeneres shortly afterwards, Selena said Brad requested a meeting with her backstage after the show.

‘I was in my dressing room and I had just finished performing,’ she told the talk show host. ‘They knocked on my door and they said Brad Pitt would like to come in and I was like, “He can come in.”

‘I was trying to play cool and be really nice,’ Selena added. ‘As soon as he walked out I ran and I hid under the craft service table for like two minutes because I couldn’t believe it was happening.’

‘He was like, “Can I have a picture with you?” I was like, “Can I have a picture with you?”‘ she laughed.

Star: Selena had a cameo role in Brad’s 2015 movie The Big Short

Brad’s part: The movie tells the story of four denizens in the world of high-finance predict the credit and housing bubble collapse of the mid-2000s

But unfortunately Selena, who later starred alongside Brad in The Big Short, didn’t manage to get her own picture.

‘It was a lot happening,’ she explained. ‘He’s so pretty.’

Meanwhile, Brad Pitt is ‘furious’ at Angelina Jolie for filing for divorce, a move he says could put their kids at risk, amid claims she told him ‘I can’t do this anymore.

Sources close to Pitt told TMZ that the actor is angry at Jolie for allegedly spinning stories about him being a potential risk to their kids because of anger issues and substance abuse.

Custody battle? Angelina has requested physical custody of the couple’s six children

Pitt reportedly said Jolie ‘unleashed hell’ because the entire family has become targets for the paparazzi while reports have also claimed that a shocking ‘incident’ may have prompted the divorce.

Over the last few days, Pitt has had conversations with Jolie pleading for her to handle the divorce ‘like adults’, sources told the site.

Pitt said he wanted to keep the divorce under wraps for the benefit of their children, but instead, he says, Jolie has painted him as a risky dad and asked for sole physical custody.

A source close to the couple told TMZ that Jolie, 41, made the decision to file because of the way ‘Brad was parenting the children,’ adding that ‘she was extremely upset with his methods’.

The Hollywood stars’ home is now surrounded by photographers, while the Los Angeles Police Department patrols regularly because of the media frenzy.

Jolie filed for divorce from Pitt for ‘the health of her family’, two years after the couple wed at their French estate Chateau Miraval.

The actress filed papers on Monday citing irreconcilable differences as the reason for the split and asked for physical custody of the couple’s six children – Maddox, age 15; Pax, aged 12; Zahara, aged 11; Shiloh, aged 10; and twins Vivienne and Knox, aged eight.

A source close to the couple told TMZ that Jolie, 41, made the decision to file because of the way ‘Brad was parenting the children,’ adding that ‘she was extremely upset with his methods’.

That same source claims Jolie became ‘fed up’ with Pitt’s consumption of ‘weed and possibly alcohol’ mixed with his ‘anger problem’.

Last seen: The couple’s last red carpet appearance was at AFI Fest last year promoting their movie By The Sea on November 5